Centro de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS) and Departamento de Química Orgánica, Facultad de Química, Universidade de Santiago de Compostela, 15782-Santiago de Compostela, Spain.
Chem Commun (Camb). 2013 Jul 18;49(56):6274-6. doi: 10.1039/c3cc43103g.
Large polyarenes with unusually complex structures can be obtained in a straightforward manner from commercially available starting materials, by means of aryne chemistry. This approach involves a sequence of tandem reactions that can be performed in one pot to give sterically congested chiral aromatic hydrocarbons that adopt highly twisted conformations.
通过芳炔化学，可以从商业上可获得的起始原料中以直接的方式得到具有异常复杂结构的大多环芳烃。该方法涉及串联反应序列，可以在一锅反应中进行，得到空间拥挤的手性芳烃，其采用高度扭曲的构象。
