National Creative Research Initiative, Center for Smart Molecular Memory, Department of Chemistry, Sungkyunkwan University, 300 Cheoncheon-dong, Jangan-gu, Suwon, Gyeonggi-do, Republic of Korea.
Chem Commun (Camb). 2013 Jul 18;49(56):6289-91. doi: 10.1039/c3cc42591f.
Changes in major charge transport of graphene channel transistors in terms of the spatial orientation of adsorbed functional molecules were demonstrated. In contrast to the horizontally (physically) bound molecules, the vertically (chemically) bound molecules did not change major charge carriers of graphene channels, revealing the molecular orientation-dependent doping effects.
研究表明,吸附功能分子的空间取向会改变石墨烯沟道晶体管的主要电荷输运。与水平(物理)结合的分子不同,垂直(化学)结合的分子不会改变石墨烯沟道的主要电荷载流子,这揭示了分子取向依赖的掺杂效应。