Graduate School of Engineering, Osaka University, 1-2 Yamadaoka, Suita, Osaka 565-087, Japan.
Angew Chem Int Ed Engl. 2013 Jul 15;52(29):7446-50. doi: 10.1002/anie.201301652. Epub 2013 Jun 5.
Silver nanoparticles (Ag NPs) of various colors were synthesized within the mesopore structure of SBA-15 by using microwave-assisted alcohol reduction. The charge density is partially localized on the surface of these Ag NPs owing to localized surface plasmon resonance. This charge localization results in them having enhanced catalytic activity under visible light irradiation compared to Ag NPs obtained by thermal processes.
采用微波辅助醇还原法,在 SBA-15 的介孔结构内合成了具有各种颜色的银纳米粒子(Ag NPs)。由于局域表面等离子体共振,这些 Ag NPs 的部分电荷定位于表面。与通过热过程获得的 Ag NPs 相比,这种电荷定位使得它们在可见光照射下具有增强的催化活性。