• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

通过聚合物在二氧化钛前驱体中的溶胀制备的纳米结构聚合物-钛复合材料及二氧化钛

Nanostructured polymer-titanium composites and titanium oxide through polymer swelling in titania precursor.

作者信息

Kierys A, Zaleski R, Buda W, Pikus S, Dziadosz M, Goworek J

机构信息

Department of Adsorption, Faculty of Chemistry, M. Curie-Sklodowska University, M. Curie-Sklodowska sq. 3, 20-031 Lublin, Poland.

出版信息

Colloid Polym Sci. 2013 Jun;291(6):1463-1470. doi: 10.1007/s00396-012-2881-x. Epub 2012 Dec 27.

DOI:10.1007/s00396-012-2881-x
PMID:23741082
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3669504/
Abstract

Polymer (XAD7HP)/Ti nanocomposites were prepared through the swelling of polymer in titanium (IV) ethoxide as a titanium dioxide precursor. The nanocomposite beads exhibit relatively high porosity different than the porosity of the initial polymer. Thermal treatment of composite particles up to 200 °C in vacuum causes the change of their internal structure. At higher temperature, the components of composite become more tightly packed. Calcination at 600 °C and total removal of polymer produce spherically shaped TiO condensed phase as determined by XRD. Thermally treated composites show the substantial change of pore dimensions within micro- and mesopores. The presence of micropores and their transformation during thermal processing was studied successfully by positron annihilation lifetime spectroscopy (PALS). The results derived from PALS experiment were compared with those obtaining from low-temperature nitrogen adsorption data.

摘要

聚合物（XAD7HP）/钛纳米复合材料是通过聚合物在作为二氧化钛前驱体的乙醇钛（IV）中溶胀来制备的。纳米复合珠粒表现出与初始聚合物孔隙率不同的相对较高的孔隙率。在真空中将复合颗粒热处理至200°C会导致其内部结构发生变化。在较高温度下，复合材料的组分堆积得更紧密。通过X射线衍射确定，在600°C下煅烧并完全去除聚合物会产生球形TiO凝聚相。热处理后的复合材料在微孔和介孔内显示出孔隙尺寸的显著变化。通过正电子湮没寿命谱（PALS）成功研究了微孔的存在及其在热加工过程中的转变。将PALS实验得到的结果与低温氮吸附数据得到的结果进行了比较。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/43234f5677d7/396_2012_2881_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/42f01fdafd8e/396_2012_2881_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/4d97f6a11332/396_2012_2881_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/d4ba57e51b5b/396_2012_2881_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/089662471652/396_2012_2881_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/c650bc3caf8f/396_2012_2881_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/43234f5677d7/396_2012_2881_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/42f01fdafd8e/396_2012_2881_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/4d97f6a11332/396_2012_2881_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/d4ba57e51b5b/396_2012_2881_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/089662471652/396_2012_2881_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/c650bc3caf8f/396_2012_2881_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8eb6/3669504/43234f5677d7/396_2012_2881_Fig6_HTML.jpg

相似文献

1
Nanostructured polymer-titanium composites and titanium oxide through polymer swelling in titania precursor.通过聚合物在二氧化钛前驱体中的溶胀制备的纳米结构聚合物-钛复合材料及二氧化钛
Colloid Polym Sci. 2013 Jun;291(6):1463-1470. doi: 10.1007/s00396-012-2881-x. Epub 2012 Dec 27.
2
Synthesis and characterization of nanostructural polymer-silica composite: positron annihilation lifetime spectroscopy study.纳米结构聚合物-二氧化硅复合材料的合成与表征：正电子湮没寿命谱研究。
J Colloid Interface Sci. 2011 Jun 1;358(1):268-76. doi: 10.1016/j.jcis.2011.03.008. Epub 2011 Mar 29.
3
Synthesis of nano titania particles embedded in mesoporous SBA-15: characterization and photocatalytic activity.嵌入介孔SBA-15的纳米二氧化钛颗粒的合成：表征与光催化活性
J Hazard Mater. 2006 Sep 21;137(2):952-8. doi: 10.1016/j.jhazmat.2006.03.017. Epub 2006 Apr 18.
4
Controllable and repeatable synthesis of thermally stable anatase nanocrystal-silica composites with highly ordered hexagonal mesostructures.可控且可重复合成具有高度有序六方介观结构的热稳定锐钛矿型纳米晶体-二氧化硅复合材料。
J Am Chem Soc. 2007 Nov 14;129(45):13894-904. doi: 10.1021/ja073804o. Epub 2007 Oct 17.
5
Efficient photocatalytic degradation of organic pollutants by magnetically recoverable nitrogen-doped TiO2 nanocomposite photocatalysts under visible light irradiation.磁性可回收的氮掺杂TiO₂纳米复合光催化剂在可见光照射下对有机污染物的高效光催化降解
Environ Sci Pollut Res Int. 2015 Dec;22(23):18859-73. doi: 10.1007/s11356-015-5032-3. Epub 2015 Jul 24.
6
Porosity evolution of VP-DVB/MCM-41 nanocomposite.VP-DVB/MCM-41 纳米复合材料的孔隙率演变。
J Colloid Interface Sci. 2010 Mar 1;343(1):134-40. doi: 10.1016/j.jcis.2009.11.019. Epub 2009 Nov 11.
7
PALS probing of photopolymerization shrinkage in densely packed acrylate-type dental restorative composites.光声寿命光谱法对密集填充丙烯酸酯类牙科修复复合材料中光聚合收缩的探测
Polim Med. 2019 Jul-Dec;49(2):49-56. doi: 10.17219/pim/118394.
8
Porous TiO(2)/SiO(2) composite prepared using PEG as template direction reagent with assistance of supercritical CO(2).以聚乙二醇为模板导向剂，在超临界二氧化碳辅助下制备的多孔TiO(2)/SiO(2)复合材料。
J Colloid Interface Sci. 2007 Dec 15;316(2):596-603. doi: 10.1016/j.jcis.2007.08.056. Epub 2007 Sep 27.
9
Three-dimensional coherent titania-mesoporous carbon nanocomposite and its lithium-ion storage properties.三维有序介孔 TiO2-碳纳米复合材料及其锂离子存储性能。
ACS Appl Mater Interfaces. 2012 Jun 27;4(6):2985-92. doi: 10.1021/am300357b. Epub 2012 Jun 4.
10
Evaluation of the Influence of Modified TiO2 Particles on Polypropylene Composites.改性二氧化钛颗粒对聚丙烯复合材料影响的评估
J Nanosci Nanotechnol. 2015 Aug;15(8):5723-32. doi: 10.1166/jnn.2015.10041.

引用本文的文献

1
Synergic Effect of TiO Filler on the Mechanical Properties of Polymer Nanocomposites.TiO填料对聚合物纳米复合材料力学性能的协同效应。
Polymers (Basel). 2021 Jun 20;13(12):2017. doi: 10.3390/polym13122017.

本文引用的文献

1
Synthesis and characterization of nanostructural polymer-silica composite: positron annihilation lifetime spectroscopy study.纳米结构聚合物-二氧化硅复合材料的合成与表征：正电子湮没寿命谱研究。
J Colloid Interface Sci. 2011 Jun 1;358(1):268-76. doi: 10.1016/j.jcis.2011.03.008. Epub 2011 Mar 29.
2
Fabrication of Porous TiO(2) Hollow Spheres and Their Application in Gas Sensing.多孔TiO₂空心球的制备及其在气体传感中的应用。
Nanoscale Res Lett. 2010 Jun 3;5(9):1437-1441. doi: 10.1007/s11671-010-9658-2.
3
Polymer/silica composite of core-shell type by polymer swelling in TEOS.
通过 TEOS 中的聚合物溶胀制备核壳型聚合物/二氧化硅复合材料。
J Colloid Interface Sci. 2010 Sep 1;349(1):361-5. doi: 10.1016/j.jcis.2010.05.049. Epub 2010 May 19.
4
A simple template-free approach to TiO2 hollow spheres with enhanced photocatalytic activity.一种简单的无模板方法制备具有增强光催化活性的 TiO2 空心球。
Dalton Trans. 2010 Jul 7;39(25):5860-7. doi: 10.1039/c0dt00053a. Epub 2010 May 27.
5
Porosity evolution of VP-DVB/MCM-41 nanocomposite.VP-DVB/MCM-41 纳米复合材料的孔隙率演变。
J Colloid Interface Sci. 2010 Mar 1;343(1):134-40. doi: 10.1016/j.jcis.2009.11.019. Epub 2009 Nov 11.
6
Novel synthesis of high-surface-area ordered mesoporous TiO2 with anatase framework for photocatalytic applications.新型高表面积有序介孔 TiO2 的合成及其在光催化中的应用。
J Colloid Interface Sci. 2010 Jan 15;341(2):359-65. doi: 10.1016/j.jcis.2009.09.058. Epub 2009 Oct 1.
7
Recent advances in sensitized mesoscopic solar cells.敏化介观太阳能电池的最新进展。
Acc Chem Res. 2009 Nov 17;42(11):1788-98. doi: 10.1021/ar900141y.
8
Rheology and UV-protecting properties of complex suspensions of titanium dioxides and zinc oxides.二氧化钛和氧化锌复合悬浮液的流变学及紫外线防护性能
J Colloid Interface Sci. 2007 Jun 15;310(2):617-23. doi: 10.1016/j.jcis.2007.02.012. Epub 2007 Feb 12.
9
Photoelectrochemical study on charge transfer properties of TiO2-B nanowires with an application as humidity sensors.TiO₂-B纳米线电荷转移特性的光电化学研究及其在湿度传感器中的应用
J Phys Chem B. 2006 Nov 2;110(43):22029-34. doi: 10.1021/jp064630k.
10
Characterization of Zr-doped TiO2 nanocrystals prepared by a nonhydrolytic sol-gel method at high temperatures.高温下通过非水解溶胶-凝胶法制备的Zr掺杂TiO₂纳米晶体的表征
J Phys Chem B. 2006 Oct 26;110(42):20808-14. doi: 10.1021/jp0626566.