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Di-μ2-chlorido-dichloridobis(dimethylformamide)tetrakis[μ3-1-(2-oxidobenzoyl)-2-(2-oxo-2-phenylethanethioyl)hydrazine-1,2-diido]octacopper(II) dimethylformamide disolvate.

作者信息

Liu Jian-Jun, Liao Jian-Zhen, Li Zuo-Yin, Wang Yao, Huang Chang-Cang

机构信息

College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, People's Republic of China.

出版信息

Acta Crystallogr C. 2013 Jun;69(Pt 6):613-5. doi: 10.1107/S0108270113012547. Epub 2013 May 17.

DOI:10.1107/S0108270113012547
PMID:23744379
Abstract

The title compound, [Cu8(C15H10N3O3S)4Cl4(C3H7NO)2]·2C3H7NO, consisting of eight Cu(II) cations, four trianionic 1-(2-oxidobenzoyl)-2-(2-oxo-2-phenylethanethioyl)hydrazine-1,2-diide ligands, four chloride ligands and two coordinated and two solvent dimethylformamide molecules, crystallizes with the octanuclear molecule located on an inversion centre. The two halves of the molecule are connected by two bridging Cl atoms. This is the first example of an octanuclear complex based on a thiosemicarbazone-derived ligand.

摘要

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引用本文的文献

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Acta Crystallogr Sect E Struct Rep Online. 2013 Nov 9;69(Pt 12):m647-8. doi: 10.1107/S1600536813030055.