Wang Jing, Jia Chunmei, Feng Xiao, Yuan Wenbing
Key Laboratory of Tropical Biological Resources of the Ministry of Education, School of Materials and Chemical Engineering, Hainan University, 58 Renmin Road, Haikou 570228, People's Republic of China.
Acta Crystallogr C Struct Chem. 2015 Sep;71(Pt 9):759-62. doi: 10.1107/S2053229615014217. Epub 2015 Aug 6.
The coordination polymer catena-poly[[(dimethylformamide-κO)μ3-5-(1,3-dioxo-4,5,6,7-tetraphenylisoindolin-2-yl)isophthalato-κ(4)O(1),O(1'):O(3):O(3')manganese(III)] dimethylformamide monosolvate], {[Mn(C40H23NO6)(CH3OH)(C3H7NO)]·C3H7NO}n, has been synthesized from the reaction of 5-(1,3-dioxo-4,5,6,7-tetraphenylisoindolin-2-yl)isophthalic acid and manganese(II) acetate tetrahydrate in a glass tube at room temperature by solvent diffusion. The Mn(II) centre is hexacoordinated by two O atoms from one chelating carboxylate group, by two O atoms from two monodentate carboxylate groups and by one O atom each from a methanol and a dimethylformamide (DMF) ligand. The single-crystal structure crystallizes in the triclinic space group P\overline{1}. Moreover, the coordination polymer shows one-dimensional 2-connected {0} uninodal chain networks, and free DMF molecules are connected to the chains by O-H···O hydrogen bonds. The thermogravimetric and photoluminescent properties of the compound have also been investigated.
