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meso-Tetrakis[4-(heptyloxy)phenyl]porphyrin.

作者信息

Zhao Hong-Bin, Chen Liang, Wang Bang-Ying, Liao Jun-Xu, Xu Yong-Jun

机构信息

College of Chemistry and Environmental Engineering, Dongguan University of Technology, Guangdong 523808, People's Republic of China.

出版信息

Acta Crystallogr C. 2013 Jun;69(Pt 6):651-3. doi: 10.1107/S0108270113011232. Epub 2013 May 15.

Abstract

The core of the novel title centrosymmetric porphyrin derivative, C72H86N4O4, with long flexible hexyloxy substituents, is almost planar, which is anticipated to facilitate π-electron delocalization and lead to a significant deviation between the planes of the benzene rings and the molecular plane. The two N-bound H atoms on the pyrrole rings are disordered and the occupancy factors refined to a ratio of 0.28 (2):0.72 (2).

摘要

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