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超薄 PtPdTe 纳米线作为甲醇电氧化的优异催化剂。

Ultrathin PtPdTe nanowires as superior catalysts for methanol electrooxidation.

机构信息

Division of Nanomaterials & Chemistry, Hefei National Laboratory for Physical Sciences at Microscale, Department of Chemistry, University of Science and Technology of China, Hefei 230026, PR China.

出版信息

Angew Chem Int Ed Engl. 2013 Jul 15;52(29):7472-6. doi: 10.1002/anie.201302090. Epub 2013 Jun 6.

DOI:10.1002/anie.201302090
PMID:23744746
Abstract

Ultrathin and ultralong: Highly uniform, ultrathin (diameter 5-7 nm), and ultralong (aspect ratio >10(4)) PtPdTe nanowires (NWs) were synthesized by using a facile method employing Te NWs as both sacrificial templates and reducing agents. Fine-tuning of the molar ratios of Pt and Pd precursors afforded PtPdTe NWs with different compositions and enhanced electroactivity in the methanol oxidation reaction in comparison with a commercial Pt/C catalyst.

摘要

超薄和超长

通过使用一种简便的方法,使用 Te NWs 作为牺牲模板和还原剂,合成了高度均匀的超薄(直径 5-7nm)和超长(纵横比>10(4))PtPdTe 纳米线(NWs)。通过精细调节 Pt 和 Pd 前体的摩尔比,可以得到具有不同组成的 PtPdTe NWs,与商业 Pt/C 催化剂相比,在甲醇氧化反应中具有增强的电活性。

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