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在非极性和极性溶剂中表现出极高荧光量子产率的 Prodan 类溶剂化变色芘类似物。

Solvatochromic pyrene analogues of Prodan exhibiting extremely high fluorescence quantum yields in apolar and polar solvents.

机构信息

Department of Organic and Polymeric Materials, Tokyo Institute of Technology, Ookayama, Tokyo 152-8552, Japan.

出版信息

Chemistry. 2013 Jul 22;19(30):9760-5. doi: 10.1002/chem.201301020. Epub 2013 Jun 6.

Abstract

True colors: Novel pyrene analogues of Prodan exhibit outstanding photophysical properties with remarkably high fluorescence quantum yield (QY) in solvents ranging from apolar hexane to polar methanol (see figure). This is accompanied by strong solvatochromism and large Stokes shifts. These properties have not been previously achieved in enormous solvatochromic dyes, but are quite useful for emitting materials and imaging tools.

摘要

真实色彩

普罗布胺的新型苝类类似物在从非极性己烷到极性甲醇的溶剂中表现出出色的光物理性质,荧光量子产率(QY)非常高(见图)。这伴随着强溶剂化变色和大斯托克斯位移。这些性质以前在巨大的溶剂化变色染料中没有实现,但对于发射材料和成像工具非常有用。

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