末端叠氮桥联 3d-4f 配合物呈现单分子磁体性质。
End-on azido-bridged 3d-4f complexes showing single-molecule-magnet property.
机构信息
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
出版信息
Inorg Chem. 2013 Jul 1;52(13):7314-6. doi: 10.1021/ic400986y. Epub 2013 Jun 7.
PMID:23746362
Abstract
Four tetranuclear 3d-4f complexes with the 4f centers bridged solely by end-on azide bridges were reported. The [CuTb]2 compound displays single-molecule-magnet behavior with hysteresis loops observed at up to 2.4 K.
摘要
报道了四个四核 3d-4f 配合物，其中 4f 中心仅通过端接的叠氮桥桥连。[CuTb]2 化合物表现出单分子磁体行为，在高达 2.4 K 的温度下观察到滞后回线。
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