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中国典型生活污水蓄留湖中环境雌激素的风险评估。

Risk assessment of xenoestrogens in a typical domestic sewage-holding lake in China.

机构信息

Key Laboratory for Green Chemical Process of Ministry of Education, Wuhan Institute of Technology, Wuhan 430073, China.

出版信息

Chemosphere. 2013 Oct;93(6):892-8. doi: 10.1016/j.chemosphere.2013.05.037. Epub 2013 Jun 5.

Abstract

Release of domestic sewage leads to accumulation of xenoestrogens in holding waters, especially in closed or semi-enclosed waters such as lakes. In the study, the occurrence, distribution, estrogenic activity and risk of eight xenoestreogens were evaluated in Lake Donghu, China. Nonylphenol (NP), octylphenol (OP), and bisphenol A (BPA) were identified as the main xenoestrogens ranging from tens of ngL(-1) (in the surface water) or ng g(-1)dw (in the suspended particles and sediment) to tens of μgL(-1) or μg g(-1)dw. The sum of 17β-estradiol equivalents (∑EEQs) ranged from 0.32 to 45.02 ngL(-1) in the surface water, 0.53 to 71.86 ng g(-1)dw in the suspended particles, and 0.09 to 24.73 ng g(-1)dw in the sediment. Diethylstilbestrol (DES) was determined as the main contributor to ∑EEQs followed by NP. The risk assessment showed a higher risk in the surface water than in the suspended particles and sediment in such domestic sewage-holding lake.

摘要

生活污水的排放会导致蓄水中的外源性雌激素累积,尤其是在湖泊等封闭或半封闭水域。本研究评估了中国东湖中 8 种外源性雌激素的发生、分布、雌激素活性及其风险。壬基酚(NP)、辛基酚(OP)和双酚 A(BPA)被鉴定为主要的外源性雌激素,其浓度范围从数十纳克/升(表层水中)或纳克/克干重(悬浮颗粒物和沉积物中)到数十微克/升或微克/克干重。表层水中的 17β-雌二醇当量(∑EEQs)的范围为 0.32 至 45.02 纳克/升,悬浮颗粒物中的范围为 0.53 至 71.86 纳克/克干重,沉积物中的范围为 0.09 至 24.73 纳克/克干重。己烯雌酚(DES)是∑EEQs 的主要贡献者,其次是 NP。风险评估显示,在这种生活污水蓄水中,表层水的风险高于悬浮颗粒物和沉积物。

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