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颌面硅橡胶中热致变色颜料的颜色稳定性

Color stability of thermochromic pigment in maxillofacial silicone.

机构信息

Vaasa Central Hospital, Vaasa, Finland. ; University of Turku, Institute of Dentistry, Department of Biomaterials Science and Turku Biomaterials Centre - TCBC, Turku, Finland.

出版信息

J Adv Prosthodont. 2013 May;5(2):75-83. doi: 10.4047/jap.2013.5.2.75. Epub 2013 May 30.

Abstract

PURPOSE

Maxillofacial silicone elastomer is usually colored intrinsically with color pigments to match skin colors. The purpose of this study was to investigate the color stability of a maxillofacial silicone elastomer, colored with a thermochromic, color changing pigment.

MATERIALS AND METHODS

Disc-shaped maxillofacial silicone specimens were prepared and divided into 3 groups: a conventionally colored control group, one group additionally colored with 0.2 wt% thermochromic pigment , and one group with 0.6 wt% thermochromic pigment. Half of the surface of each specimen was covered with an aluminium foil. All of the specimens were exposed to UV radiation in 6 hour cycles over 46 days. In between the UV exposures, half of the specimens were stored in darkness, at room temperature, and the other half was stored in an incubator, at a humidity of 97% and a temperature of +37℃. Color measurements were made with a spectrophotometer and registered according to the CIELAB L()a()b() color model system. The changes in L(), a() and b() values during artificial aging were statistically analyzed by using paired samples t-test and repeated measures ANOVA. P-values <.05 were considered as statistically significant.

RESULTS

The UV exposure resulted in visually noticeable and statistically significant color changes in the L(), a() and b() values in both of the test groups containing thermochromic pigment. Storage in the incubator lead to statistically significant color changes in the a() and b(*) values of the specimens containing thermochromic pigment, compared to those stored at room temperature.

CONCLUSION

The specimens containing thermochromic pigment were very sensitive to UV radiation, and the thermochromic pigment is not suitable, as such, to be used in maxillofacial prostheses.

摘要

目的

颌面硅橡胶弹性体通常通过颜色颜料进行内在着色以匹配肤色。本研究的目的是研究一种颌面硅橡胶弹性体的颜色稳定性,该弹性体用热致变色、颜色变化颜料进行着色。

材料与方法

制备圆盘状颌面硅橡胶标本并将其分为 3 组:常规着色的对照组、一组额外用 0.2wt%热致变色颜料着色的组和一组用 0.6wt%热致变色颜料着色的组。每个标本的一半表面用铝箔覆盖。所有标本均在 46 天内以 6 小时为周期暴露于 UV 辐射下。在 UV 暴露之间,一半标本在室温下存放在暗处,另一半在湿度为 97%和温度为+37℃的培养箱中储存。用分光光度计进行颜色测量,并根据 CIELAB L()a()b()颜色模型系统进行记录。通过配对样本 t 检验和重复测量 ANOVA 对人工老化过程中 L()、a()和 b()值的变化进行统计学分析。P 值<.05 被认为具有统计学意义。

结果

UV 暴露导致含有热致变色颜料的两组测试标本的 L()、a()和 b()值发生明显且具有统计学意义的颜色变化。与在室温下储存的标本相比,在培养箱中储存会导致含有热致变色颜料的标本的 a()和 b(*)值发生具有统计学意义的颜色变化。

结论

含有热致变色颜料的标本对 UV 辐射非常敏感,因此,热致变色颜料不适合用于颌面修复体。

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