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阳极氧化铝模板压印对柔性染料敏化太阳能电池TiO2阻挡层的影响。

Effect of anodic aluminum oxide template imprinting on TiO2 blocking layer of flexible dye-sensitized solar cell.

作者信息

Kim Kang-Pil, Lee Sang-Ju, Kim Dae-Hwan, Hwang Dae-Kue

机构信息

Green Energy Research Division, Daegu-Gyeongbuk Institute of Science and Technology (DGIST), 50-1, Sang-ri, Hyeonpung-myeon, Dalseong-Gun, Daegu 711-873, South Korea.

出版信息

J Nanosci Nanotechnol. 2013 Mar;13(3):1888-90. doi: 10.1166/jnn.2013.6983.

Abstract

In this paper, we have proposed a new flexible dye-sensitized solar cell (DSSC) structure that employs an Anodic Aluminum Oxide (AAO) template imprinted TiO2 blocking layer, in which the AAO template creates TiO2 nano-particle aggregated islands on the TiO2 blocking layer. The TiO2 blocking layer prevents charge recombination between the metal foil and the liquid electrolyte. TiO2 nano-particle aggregated islands improve the scattering of incident light during back illumination and provide the wider surface area, yielding enhanced power conversion efficiency (PCE). All the flexible DSSC structure with TiO2 nano-particle aggregated islands on the TiO2 blocking layer exhibited higher photocurrent than did conventional DSSC because light that passed through the photoanode was scattered, thereby giving it improved PCE that was as much as 23% higher than that of a conventional DSSC. This proposed method is an effective manufacturing process for flexible DSSC.

摘要

在本文中,我们提出了一种新型的柔性染料敏化太阳能电池(DSSC)结构,该结构采用了阳极氧化铝(AAO)模板压印的TiO₂阻挡层,其中AAO模板在TiO₂阻挡层上形成了TiO₂纳米颗粒聚集岛。TiO₂阻挡层可防止金属箔与液体电解质之间的电荷复合。TiO₂纳米颗粒聚集岛可改善背照光期间入射光的散射,并提供更宽的表面积,从而提高功率转换效率(PCE)。所有在TiO₂阻挡层上具有TiO₂纳米颗粒聚集岛的柔性DSSC结构均表现出比传统DSSC更高的光电流,这是因为穿过光阳极的光发生了散射,从而使其PCE提高,比传统DSSC高出多达23%。该方法是一种用于柔性DSSC的有效制造工艺。

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