State Key Lab of Urban Water Resource and Environment (SKLUWRE) & Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin, Heilongjiang 150080, PR China.
Chem Commun (Camb). 2013 Jul 21;49(57):6433-5. doi: 10.1039/c3cc42673d.
Chiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.
手性 N-叔丁基亚磺酰基乙烯基氮丙啶配体由易得的 (R)-叔丁基亚磺酰胺制备，已应用于铑催化的芳基硼酸对环状烯酮的不对称 1,4-加成反应，该反应具有高产率和优异的对映选择性。
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