迈向甲酸制氢实用化装置。
Towards a practical setup for hydrogen production from formic acid.
机构信息
Leibniz-Institut für Katalyse eV an der Universität Rostock, Rostock, Germany.
出版信息
ChemSusChem. 2013 Jul;6(7):1172-6. doi: 10.1002/cssc.201300186. Epub 2013 Jun 11.
PMID:23757329
Abstract
Formic acid cracker: A mini plant that allows for continuous formic acid decomposition to hydrogen and carbon dioxide under ambient conditions is presented. By using an in situ-formed ruthenium catalyst, unprecedented turnover numbers over 1,000,000 are achieved. The active catalyst is formed in situ from commercially available [RuCl2 (benzene)]2 and 1,2-bisdiphenylphosphinoethane.
摘要
甲酸 crackers：一种迷你装置，可以在环境条件下连续分解甲酸为氢气和二氧化碳。通过使用原位形成的钌催化剂，实现了超过 100 万的空前转化率。活性催化剂是由市售的[RuCl2(苯)]2和 1,2-双二苯基膦乙烷原位形成的。
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