State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, PR China.
ChemSusChem. 2013 Jul;6(7):1149-52. doi: 10.1002/cssc.201300318. Epub 2013 Jun 11.
Our best results jet: C10 and C11 branched alkanes, with low freezing points, are synthesized through the aldol condensation of furfural and methyl isobutyl ketone from lignocellulose, which is then followed by hydrodeoxygenation. These jet-fuel-range alkanes are obtained in high overall yields (≈90%) under solvent-free conditions.
C10 和 C11 支链烷烃,其冰点低,通过木质纤维素中的糠醛和甲基异丁基酮的醇醛缩合反应合成,然后进行加氢脱氧。在无溶剂条件下,这些喷气燃料范围内的烷烃以高总收率(约 90%)获得。