• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

无溶剂条件下由糠醛和甲基异丁基酮合成 C10 和 C11 支链烷烃

Solvent-free synthesis of C10 and C11 branched alkanes from furfural and methyl isobutyl ketone.

机构信息

State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, PR China.

出版信息

ChemSusChem. 2013 Jul;6(7):1149-52. doi: 10.1002/cssc.201300318. Epub 2013 Jun 11.

DOI:10.1002/cssc.201300318
PMID:23757334
Abstract

Our best results jet: C10 and C11 branched alkanes, with low freezing points, are synthesized through the aldol condensation of furfural and methyl isobutyl ketone from lignocellulose, which is then followed by hydrodeoxygenation. These jet-fuel-range alkanes are obtained in high overall yields (≈90%) under solvent-free conditions.

摘要

我们得到的最佳结果是

C10 和 C11 支链烷烃,其冰点低,通过木质纤维素中的糠醛和甲基异丁基酮的醇醛缩合反应合成,然后进行加氢脱氧。在无溶剂条件下,这些喷气燃料范围内的烷烃以高总收率(约 90%)获得。

相似文献

1
Solvent-free synthesis of C10 and C11 branched alkanes from furfural and methyl isobutyl ketone.无溶剂条件下由糠醛和甲基异丁基酮合成 C10 和 C11 支链烷烃
ChemSusChem. 2013 Jul;6(7):1149-52. doi: 10.1002/cssc.201300318. Epub 2013 Jun 11.
2
Direct Synthesis of Renewable Dodecanol and Dodecane with Methyl Isobutyl Ketone over Dual-Bed Catalyst Systems.双床层催化剂体系中甲基异丁基酮直接合成可再生十二醇和十二烷
ChemSusChem. 2017 Mar 9;10(5):825-829. doi: 10.1002/cssc.201601563. Epub 2017 Jan 18.
3
Synthesis of Renewable Lubricant Alkanes from Biomass-Derived Platform Chemicals.由生物质衍生的平台化学品合成可再生润滑剂烷烃。
ChemSusChem. 2017 Oct 23;10(20):4102-4108. doi: 10.1002/cssc.201701200. Epub 2017 Sep 27.
4
One-pot aldol condensation and hydrodeoxygenation of biomass-derived carbonyl compounds for biodiesel synthesis.用于生物柴油合成的生物质衍生羰基化合物的一锅法羟醛缩合和加氢脱氧反应
ChemSusChem. 2014 Oct;7(10):2816-20. doi: 10.1002/cssc.201402236. Epub 2014 Aug 1.
5
Lignocellulose fractionation into furfural and glucose by AlCl-catalyzed DES/MIBK biphasic pretreatment.AlCl3 催化的 DES/MIBK 双相预处理将木质纤维素分馏为糠醛和葡萄糖。
Int J Biol Macromol. 2018 Oct 1;117:721-726. doi: 10.1016/j.ijbiomac.2018.05.232. Epub 2018 Jun 1.
6
Efficient hydrodeoxygenation of biomass-derived ketones over bifunctional Pt-polyoxometalate catalyst.在双功能 Pt-多金属氧酸盐催化剂上高效加氢脱氧生物质衍生的酮。
Chem Commun (Camb). 2012 Jul 21;48(57):7194-6. doi: 10.1039/c2cc33189f. Epub 2012 Jun 11.
7
Production of Low-Freezing-Point Highly Branched Alkanes through Michael Addition.通过迈克尔加成法生产低冰点高支化烷烃。
ChemSusChem. 2017 Dec 22;10(24):4817-4823. doi: 10.1002/cssc.201701789. Epub 2017 Nov 21.
8
Selective One-Pot Production of High-Grade Diesel-Range Alkanes from Furfural and 2-Methylfuran over Pd/NbOPO.在Pd/NbOPO上由糠醛和2-甲基呋喃选择性一锅法制备高品位柴油馏分烷烃
ChemSusChem. 2017 Feb 22;10(4):747-753. doi: 10.1002/cssc.201601522. Epub 2016 Nov 22.
9
Conversion of raw lignocellulosic biomass into branched long-chain alkanes through three tandem steps.通过三个串联步骤将原始木质纤维素生物质转化为支链长链烷烃。
ChemSusChem. 2016 Jul 7;9(13):1712-8. doi: 10.1002/cssc.201600386. Epub 2016 May 31.
10
Diesel and alkane fuels from biomass by organocatalysis and metal-acid tandem catalysis.生物质的有机催化和金属-酸串联催化制备柴油和烷烃燃料。
ChemSusChem. 2013 Dec;6(12):2236-9. doi: 10.1002/cssc.201300476. Epub 2013 Aug 12.

引用本文的文献

1
Research progress of catalysts for aldol condensation of biomass based compounds.生物质基化合物羟醛缩合催化剂的研究进展
RSC Adv. 2023 Mar 23;13(14):9466-9478. doi: 10.1039/d3ra00906h. eCollection 2023 Mar 20.
2
Controlled hydrogenation of a biomass-derived platform chemical formed by aldol-condensation of 5-hydroxymethyl furfural (HMF) and acetone over Ru, Pd, and Cu catalysts.由5-羟甲基糠醛(HMF)和丙酮经羟醛缩合形成的生物质衍生平台化学品在Ru、Pd和Cu催化剂上的可控氢化反应。
Green Chem. 2022 Mar 7;24(5):2146-2159. doi: 10.1039/d1gc04650k. Epub 2022 Feb 9.
3
Solvent-Free Hydrogenation of Squalene Using Parts per Million Levels of Palladium Supported on Carbon Nanotubes: Shift from Batch Reactor to Continuous-Flow System.
使用负载在碳纳米管上的百万分之几水平的钯进行角鲨烯的无溶剂氢化:从间歇式反应器到连续流系统的转变。
ChemSusChem. 2022 Oct 10;15(19):e202200916. doi: 10.1002/cssc.202200916. Epub 2022 Aug 25.
4
Tandem Reactions for the Synthesis of High-Density Polycyclic Biofuels with a Double/Triple Hexane Ring.用于合成具有双/三环己烷环的高密度多环生物燃料的串联反应。
ACS Omega. 2022 May 30;7(23):19158-19165. doi: 10.1021/acsomega.1c07241. eCollection 2022 Jun 14.
5
Production of renewable long-chained cycloalkanes from biomass-derived furfurals and cyclic ketones.由生物质衍生的糠醛和环酮制备可再生长链环烷烃。
RSC Adv. 2018 Apr 12;8(25):13686-13696. doi: 10.1039/c8ra01723a. eCollection 2018 Apr 11.
6
Efficient synthesis of C fuel precursor by heterogeneously catalyzed aldol-condensation of furfural with cyclopentanone.通过糠醛与环戊酮的多相催化羟醛缩合高效合成C燃料前驱体。
RSC Adv. 2019 Jan 28;9(7):3661-3668. doi: 10.1039/c8ra09517e. eCollection 2019 Jan 25.
7
Synthesis of jet fuel range branched cycloalkanes with mesityl oxide and 2-methylfuran from lignocellulose.利用木质纤维素合成喷气燃料范围内的支链环烷烃与均三甲苯氧化物和 2-甲基呋喃。
Sci Rep. 2016 Sep 1;6:32379. doi: 10.1038/srep32379.