利用木质纤维素合成喷气燃料范围内的支链环烷烃与均三甲苯氧化物和 2-甲基呋喃。
Synthesis of jet fuel range branched cycloalkanes with mesityl oxide and 2-methylfuran from lignocellulose.
机构信息
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Graduate University of Chinese Academy of Sciences, Beijing 10049, China.
出版信息
Sci Rep. 2016 Sep 1;6:32379. doi: 10.1038/srep32379.
Jet fuel range branched cycloalkanes with high density (0.82 g mL(-1)) and low freezing point (217-219 K) was first prepared by the solvent-free intramolecular aldol condensation of the trione from the hydrolysis of the alkylation product of mesityl oxide and 2-methylfuran (or the one-pot reaction of mesityl oxide, 2-methylfuran and water), followed by hydrodeoxygenation (HDO).
首先通过间苯二酚、2-甲基呋喃和水的一锅法反应，或者间苯二甲基氧化物与 2-甲基呋喃的烷基化产物水解得到的三酮的无溶剂分子内羟醛缩合反应，制备出具有高密度（0.82 g/mL）和低冰点（217-219 K）的喷气燃料支链环烷烃，然后进行加氢脱氧（HDO）。
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