一种新型高效合成取代烯烃的方法；使用 NaHSO4/SiO2 交叉偶联两种不同的醇。
A novel efficient method for the synthesis of substituted olefins; cross coupling of two different alcohols using NaHSO4/SiO2.
机构信息
Department of Materials and Applied Chemistry, College of Science and Technology, Nihon University, Kanda Surugadai, Tokyo, Japan.
出版信息
Chem Commun (Camb). 2013 Jul 28;49(59):6605-7. doi: 10.1039/c3cc42746c.
PMID:23770760
Abstract
Simple and efficient cross coupling of alcohols was developed in the presence of NaHSO4/SiO2 to give the corresponding substituted olefins. Direct coupling of alcohols and alkenes was also achieved to give substituted olefins. NaHSO4/SiO2 could be recycled 7 times without loss of catalytic activity.
摘要
在 NaHSO4/SiO2 的存在下，开发了一种简单高效的醇交叉偶联反应，得到相应的取代烯烃。醇和烯烃的直接偶联也可以得到取代烯烃。NaHSO4/SiO2 可以回收 7 次而不失去催化活性。
Zotero 插件