铜催化串联氧化-烯烃化反应过程
Copper-catalyzed tandem oxidation-olefination process.
作者信息
Davi Michaël, Lebel Hélène
机构信息
Departement de Chimie, Universite de Montreal, 2900 Boul. Edouard Montpetit, Montreal, Quebec, Canada H3T 1J4.
出版信息
Org Lett. 2009 Jan 1;11(1):41-4. doi: 10.1021/ol802299d.
PMID:19061362
Abstract
A novel catalytic sequence aerobic oxidation-olefination has been developed. A single and inexpensive copper catalyst provides a large range of olefins from alcohols in good to excellent yields. The reaction exhibits excellent functional group compatibility, and the nonbasic reaction conditions allow the transformation of chiral substrates without racemization.
摘要
已开发出一种新型催化序列有氧氧化-烯化反应。单一且廉价的铜催化剂能以良好至优异的产率从醇类制备多种烯烃。该反应具有出色的官能团兼容性，且非碱性反应条件允许手性底物在不发生外消旋化的情况下进行转化。
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