Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan.
Chemistry. 2013 Jul 15;19(29):9420-7. doi: 10.1002/chem.201300908. Epub 2013 Jun 17.
In this paper, new possibilities for metal amides are described. Although typical metal amides are recognized as strong stoichiometric bases for deprotonation of inert or less acidic hydrogen atoms, transition-metal amides, namely silver and copper amides, show interesting abilities as one of the simplest acid/base catalysts in stereoselective carbon-carbon bond-forming reactions.
本文描述了金属酰胺的新可能性。尽管典型的金属酰胺被认为是强的化学计量碱，可以使惰性或酸性较弱的氢原子去质子化，但过渡金属酰胺，即银和铜酰胺，在立体选择性碳-碳键形成反应中作为最简单的酸碱催化剂之一，表现出有趣的能力。
