从1,6-脱水-β-D-吡喃葡萄糖（左旋葡聚糖）立体控制合成兰卡内酯：1，C-1/7和C-8/15片段的合成。
Stereocontrolled synthesis of lankanolide from 1,6-anhydro-beta-D-glucopyranose (levoglucosan): 1, synthesis of the C-1/7 and C-8/15 segments.
作者信息
Kochetkov N K, Yashunsky D V, Sviridov A F, Ermolenko M S
机构信息
N.D. Zelinksky Institute of Organic Chemistry, Academy of Sciences of the U.S.S.R., Moscow.
出版信息
Carbohydr Res. 1990 Apr 25;200:209-25. doi: 10.1016/0008-6215(90)84192-w.
PMID:2379206
Abstract
A scheme has been designed for the stereocontrolled synthesis of lankanolide, the aglycon of lankamycin. Synthesis of its C-1/7 and C-8/15 segments has been accomplished starting from 1,6-anhydro-2,4-dideoxy-2,4-di-C-methyl-beta-D-glucopyranose.
摘要
已设计出一种用于立体控制合成兰卡内酯（兰卡霉素的苷元）的方案。从1,6-脱水-2,4-二脱氧-2,4-二-C-甲基-β-D-吡喃葡萄糖开始，已完成其C-1/7和C-8/15片段的合成。
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