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2-（4-溴苯基）-N-（3,4-二氟苯基）乙酰胺

2-(4-Bromo-phen-yl)-N-(3,4-di-fluoro-phen-yl)acetamide.

作者信息

Praveen A S, Yathirajan H S, Jasinski Jerry P, Keeley Amanda C, Narayana B, Sarojini B K

机构信息

Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 May 18;69(Pt 6):o900-1. doi: 10.1107/S1600536813012865. Print 2013 Jun 1.

DOI:10.1107/S1600536813012865
PMID:23795076
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3685057/
Abstract

In the title compound, C14H10BrF2NO, the dihedral angle between the mean planes of the 4-bromo-phenyl and 3,4-di-fluoro-phenyl rings is 66.4 (1)°. These two planes are twisted by 40.0 (5) and 86.3 (2)°, respectively, from that of the acetamide group. In the crystal, N-H⋯O hydrogen bonds and weak C-H⋯O and C-H⋯F inter-actions form infinite chains along [100].

摘要

在标题化合物C₁₄H₁₀BrF₂NO中，4-溴苯基和3,4-二氟苯基环的平均平面之间的二面角为66.4 (1)°。这两个平面相对于乙酰胺基团的平面分别扭转了40.0 (5)°和86.3 (2)°。在晶体中，N-H⋯O氢键以及弱的C-H⋯O和C-H⋯F相互作用沿着[100]形成无限链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ff9/3685057/cf17ce016baf/e-69-0o900-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ff9/3685057/db298a1866f5/e-69-0o900-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ff9/3685057/bfb0cc09114a/e-69-0o900-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ff9/3685057/cf17ce016baf/e-69-0o900-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ff9/3685057/db298a1866f5/e-69-0o900-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ff9/3685057/bfb0cc09114a/e-69-0o900-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ff9/3685057/cf17ce016baf/e-69-0o900-fig3.jpg

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