LUNAM Université, Université d'Angers, CNRS UMR 6200, Laboratoire MOLTECH-Anjou, 2 bd Lavoisier, 49045 Angers Cedex, France.
J Am Chem Soc. 2013 Jul 10;135(27):10018-21. doi: 10.1021/ja404072w. Epub 2013 Jun 27.
Two original self-assembled containers constituted each by six electroactive subunits are described. They are synthesized from a concave tetratopic π-extended tetrathiafulvalene ligand bearing four pyridyl units and cis-M(dppf)(OTf)2 (M = Pd or Pt; dppf = 1,1'-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both fully characterized assemblies present an oblate spheroidal cavity that can incorporate one perylene molecule.
描述了两种由六个电活性亚基组成的原始自组装容器。它们是由具有四个吡啶单元的凹四面体型π-扩展四噻吩并[3,2-b:2',3'-d]噻吩配体和 cis-M(dppf)(OTf)2（M = Pd 或 Pt；dppf = 1,1'-双（二苯基膦）二茂铁；OTf = 三氟甲磺酸）配合物合成的。这两种完全表征的组装体都呈现出扁球形空腔，可以容纳一个苝分子。
