Department of Physics, Niğde University, 51240, Niğde, Turkey.
J Phys Chem B. 2013 Aug 1;117(30):8931-8. doi: 10.1021/jp402219t. Epub 2013 Jul 8.
The dielectric properties of methylene blue (MB)-doped hydrogels were investigated by impedance spectroscopy. The real part (ε') and the imaginary part (ε") of the complex dielectric constant and the energy loss tangent/dissipation factor (tan δ) were measured in the frequency range of 10 Hz to 100 MHz at room temperature for pH 5.5 value. Frequency variations of the resistance, the reactance, and the impedance of the samples have also been investigated. The dielectric permittivity of the MB-doped hydrogels is sensitive to ionic conduction and electrode polarization in low frequency. Furthermore, the dielectric behavior in high-frequency parts was attributed to the Brownian motion of the hydrogen bonds. The ionic conduction for MB-doped samples was prevented for Cole-Cole plots, while the Cole-Cole plots for pure sample show equivalent electrical circuit. The alternative current (ac) conductivity increases with the increasing MB concentration and the frequency.
采用阻抗谱法研究了亚甲蓝(MB)掺杂水凝胶的介电性能。在室温下,pH 值为 5.5 时,测量了频率范围为 10 Hz 至 100 MHz 下复介电常数的实部(ε')和虚部(ε")以及能量损耗正切/耗散因子(tan δ)。还研究了样品的电阻、电抗和阻抗随频率的变化。MB 掺杂水凝胶的介电常数对低频下的离子传导和电极极化敏感。此外,高频部分的介电行为归因于氢键的布朗运动。对于科尔-科尔图,MB 掺杂样品的离子传导被阻止,而纯样品的科尔-科尔图显示等效电路。交流(ac)电导率随 MB 浓度和频率的增加而增加。