College of Chemistry and Chemical Engineering, Key Laboratory of Nanomagnetic and Functional Materials, Inner Mongolia University, 010021, Hohhot, PR China.
Chem Commun (Camb). 2013 Aug 7;49(61):6897-9. doi: 10.1039/c3cc43168a. Epub 2013 Jun 26.
A novel 3D microporous compound [Zn3(Httca)2(4,4'-bpy)(H2O)2]n (MOF-COOH) containing uncoordinated carbonyl groups pointing to the pores was prepared. The uncoordinated carbonyl groups in the channels can act as postsynthetic modification sites for cation exchange. The MOF-COOH compound can effectively and selectively serve as an antenna for sensitizing the visible-emitting Tb(3+) cation.
一种新型的 3D 微孔化合物 [Zn3(Httca)2(4,4'-bpy)(H2O)2]n（MOF-COOH）被制备出来，其中含有指向孔道的未配位的羰基基团。通道中的未配位羰基基团可以作为后合成修饰位点，用于进行阳离子交换。MOF-COOH 化合物可以有效地、选择性地作为敏化可见光发射 Tb(3+)阳离子的天线。
