Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain.
Dalton Trans. 2013 Aug 21;42(31):11039-42. doi: 10.1039/c3dt51562a.
The sequential addition of H⁺ and H⁻ ions to [Mo₂Cp₂(μ-κ²P,S:κ¹P,η⁴-SPMes*)(CNtBu)(CO)₂] (Mes* = 2,4,6-C₆H₂tBu₃) completes a hydrocarbation or hydronitration of the uncoordinated C=C bond of the Mes* ring, yielding new ligands with thiophosphinidene and aldimine or aminocarbene functions tethered to a η⁴-cyclohexadiene ring. The H⁻ ion first attacks a Cp group to give a cyclopentadiene complex which evolves via a hydride intermediate.
质子（H⁺）和氢负离子（H⁻）依次加成于 [Mo₂Cp₂(μ-κ²P,S:κ¹P,η⁴-SPMes*)(CNtBu)(CO)₂]（Mes* = 2,4,6-C₆H₂tBu₃），完成了 Mes* 环中未配位的 C=C 键的加氢或加氢氮反应，生成了具有膦亚氨基和亚胺或氨基卡宾功能的新配体，这些配体通过 η⁴-环己二烯环连接。氢负离子首先攻击一个 Cp 基团，生成环戊二烯配合物，该配合物通过氢化物中间体进行演化。
