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Development of a Double Allylboration Reagent Targeting 1,5-syn-(E)-Diols: Application to the Synthesis of the C(23)-C(40) Fragment of Tetrafibricin.
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Diastereo- and enantioselective reductive aldol reaction with trichlorosilane using chiral Lewis bases as organocatalysts.
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CuH-catalyzed enantioselective intramolecular reductive aldol reactions generating three new contiguous asymmetric stereocenters.
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