有机合成中 C-P 键形成的磷分子均裂取代反应。
Homolytic substitution at phosphorus for C-P bond formation in organic synthesis.
机构信息
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan ; ACT-C, Japan Science and Technology Agency, Sakyo-ku, Kyoto 606-8502, Japan.
出版信息
Beilstein J Org Chem. 2013 Jun 28;9:1269-77. doi: 10.3762/bjoc.9.143. Print 2013.
Organophosphorus compounds are important in organic chemistry. This review article covers emerging, powerful synthetic approaches to organophosphorus compounds by homolytic substitution at phosphorus with a carbon-centered radical. Phosphination reagents include diphosphines, chalcogenophosphines and stannylphosphines, which bear a weak P-heteroatom bond for homolysis. This article deals with two transformations, radical phosphination by addition across unsaturated C-C bonds and substitution of organic halides.
有机磷化合物在有机化学中很重要。本文综述了通过磷原子与碳自由基的均裂取代来合成有机磷化合物的新兴、强大的合成方法。膦化试剂包括二膦、硒代膦和锡代膦，它们具有较弱的 P-杂原子键，可进行均裂。本文涉及两种转化，即不饱和 C-C 键加成的自由基膦化和有机卤化物的取代。
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