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通过 C-P 键形成制备膦。

Preparation of phosphines through C-P bond formation.

机构信息

Research Group SynBioC, Department of Sustainable Organic Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Coupure links 653, 9000 Ghent, Belgium.

出版信息

Beilstein J Org Chem. 2014 May 9;10:1064-96. doi: 10.3762/bjoc.10.106. eCollection 2014.

Abstract

Phosphines are an important class of ligands in the field of metal-catalysis. This has spurred the development of new routes toward functionalized phosphines. Some of the most important C-P bond formation strategies were reviewed and organized according to the hybridization of carbon in the newly formed C-P bond.

摘要

膦是金属催化领域中一类重要的配体。这促使人们开发出了新的合成功能化膦的路线。本文按照新形成的 C-P 键中碳原子的杂化方式对一些最重要的 C-P 键形成策略进行了综述和分类。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7780/4077473/348d710c2bb6/Beilstein_J_Org_Chem-10-1064-g003.jpg

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