Materials Chemistry Group, Department of Chemistry, University of Delhi, Delhi 110007, India.
Chem Commun (Camb). 2013 Aug 25;49(66):7316-8. doi: 10.1039/c3cc43456g.
A facile precursor dependent single step, one pot solution based synthesis of wurtzite and chalcopyrite polymorphs of CuFeS2 has been developed by reacting a Cu(I) thiourea complex with Fe2(SO4)3 and FeCl3 separately in ethylene glycol. The phases have been characterized by structural refinements, SEM-EDX, TEM-SAED, Raman, UV-Visible spectroscopy and TGA measurements.
一种简便的前驱物依赖的一步法、一锅法溶液合成了纤锌矿和黄铜矿型的 CuFeS2，方法是分别在乙二醇中用 Cu(I)硫脲配合物与 Fe2(SO4)3 和 FeCl3 反应。通过结构精修、SEM-EDX、TEM-SAED、拉曼、UV-Visible 光谱和 TGA 测量对各相进行了表征。
