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锆基三色颜料对新型牙科二硅酸锂微晶玻璃颜色、微观结构、抗弯强度和透明度的影响

Effect of zircon-based tricolor pigments on the color, microstructure, flexural strength and translucency of a novel dental lithium disilicate glass-ceramic.

作者信息

Yuan Kun, Wang Fu, Gao Jing, Sun Xiang, Deng Zai-Xi, Wang Hui, Jin Lei, Chen Ji-Hua

机构信息

Department of Prosthodontics, School of Stomatology, Fourth Military Medical University, Xi'an, 710032, China.

出版信息

J Biomed Mater Res B Appl Biomater. 2014 Jan;102(1):98-107. doi: 10.1002/jbm.b.32986. Epub 2013 Jul 13.

Abstract

The purpose of this study was to investigate the effect of zircon-based tricolor pigments (praseodymium zircon yellow, ferrum zircon red, and vanadium zircon blue) on the color, thermal property, crystalline phase composition, microstructure, flexural strength, and translucency of a novel dental lithium disilicate glass-ceramic. The pigments were added to the glass frit, milled, pressed, and sintered. Ninety monochrome samples were prepared and the colors were analyzed. The effect of the pigments on thermal property, crystalline phase composition, and microstructure were determined by differential scanning calorimetry (DSC), X-ray diffraction (XRD), and scanning electron microscopy (SEM), respectively. Addition of the pigments resulted in the acquisition of subtractive primary colors as well as tooth-like colors, and did not demonstrate significant effects on the thermal property, crystalline phase composition, microstructure, and flexural strength of the experimental glass-ceramic. Although significant differences (p < 0.01) were observed between the translucencies of the uncolored and 1.0 wt % zircon-based pigment colored ceramics, the translucencies of the latter were sufficient to fabricate dental restorations. These results indicate that the zircon-based tricolor pigments can be used with dental lithium disilicate glass-ceramic to produce abundant and predictable tooth-like colors without significant adverse effects, if mixed in the right proportions.

摘要

本研究的目的是探究锆基三色颜料(镨锆黄、铁锆红和钒锆蓝)对一种新型牙科二硅酸锂微晶玻璃的颜色、热性能、晶相组成、微观结构、弯曲强度和半透明度的影响。将颜料添加到玻璃料中,进行研磨、压制和烧结。制备了90个单色样品并对颜色进行分析。分别通过差示扫描量热法(DSC)、X射线衍射(XRD)和扫描电子显微镜(SEM)测定颜料对热性能、晶相组成和微观结构的影响。添加颜料可获得减色法三原色以及类似牙齿的颜色,且对实验性微晶玻璃的热性能、晶相组成、微观结构和弯曲强度未显示出显著影响。尽管未着色陶瓷与1.0 wt%锆基颜料着色陶瓷的半透明度之间观察到显著差异(p < 0.01),但后者的半透明度足以用于制作牙科修复体。这些结果表明,如果以正确比例混合,锆基三色颜料可与牙科二硅酸锂微晶玻璃一起使用,以产生丰富且可预测的类似牙齿的颜色,且无明显不良影响。

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