首例杂双核双硼烯配合物的合成与结构
Synthesis and structure of the first heterodinuclear bis(borylene) complexes.
机构信息
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074, Würzburg, Germany.
出版信息
Chem Commun (Camb). 2013 Sep 7;49(69):7593-5. doi: 10.1039/c3cc43877e. Epub 2013 Jul 22.
PMID:23873145
Abstract
We report a facile synthesis of the first heterodinuclear bis(borylene) complex by reaction of an iron bis(borylene) complex with [Pt(PCy3)2], and its fully-reversible CO uptake and liberation reaction.
摘要
我们报告了首例异双核双硼烯配合物的简便合成方法，该配合物通过铁双硼烯配合物与[Pt(PCy3)2]反应得到，并具有完全可逆的 CO 吸脱附反应。
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