Povarov 还原胺化级联反应构建 6-氨基喹啉和蒽唑啉。
Povarov-reductive amination cascade to access 6-aminoquinolines and anthrazolines.
机构信息
Department of Chemistry, Acadia University, Wolfville, NS, B4P 2R6, Canada.
出版信息
Org Lett. 2013 Aug 16;15(16):4078-81. doi: 10.1021/ol4016354. Epub 2013 Jul 26.
PMID:23889262
Abstract
A new strategy is reported for the synthesis of 6-aminoquinoline derivatives via a tandem Povarov reaction, dihydroquinoline oxidation, and imine reduction. These products allow access to symmetrical as well as unsymmetrical tetraarylpyrido[2,3-g]quinolines, potentially useful organic electronics.
摘要
报道了一种通过串联 Povarov 反应、二氢喹啉氧化和亚胺还原合成 6-氨基喹啉衍生物的新策略。这些产物可以得到对称和不对称的四芳基吡啶并[2,3-g]喹啉，它们可能是有用的有机电子材料。
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