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将含 Pb 的阴极射线管废物掺入自密实混凝土过程中使用石灰石粉。

Use of limestone powder during incorporation of Pb-containing cathode ray tube waste in self-compacting concrete.

机构信息

Department of Building Technology Faculty of Industrial Technology, Phranakhon Rajabhat University, 9 Changwattana Road, Bangkhen, Bangkok 10220, Thailand.

出版信息

J Environ Manage. 2013 Oct 15;128:931-40. doi: 10.1016/j.jenvman.2013.06.031. Epub 2013 Jul 24.

Abstract

For several decades, cathode ray tubes (CRTs) were the primary display component of televisions and computers. The CRT glass envelope contains sufficient levels of lead oxide (PbO) to be considered hazardous, and there is a need for effective methods of permanently encapsulating this material during waste disposal. We examined the effect of adding limestone powder (LS) on the fresh and cured properties of self-compacting concrete (SCC) mixtures containing waste CRT glass. The SCC mixtures were prepared using Type 1 Portland cement at a constant cement content of 600 kg/m(3) and a water-to-cement ratio (w/c) of 0.38. CRT glass waste cullet was blended with river sand in proportions of 20 or 40% by weight. To suppress potential viscosity effects limestone powder was added at levels of 5, 10, or 15% by weight. The slump flow time, slump flow diameter, V-funnel flow time, Marsh cone flow time, and setting time of the fresh concrete were tested, as well as the compressive strength and ultrasonic pulse velocity of the hardened concrete. Addition of limestone powder improved the fresh and hardened properties. Pb leaching levels from the cured concrete were within US EPA allowable limits.

摘要

几十年来,阴极射线管(CRT)一直是电视和计算机的主要显示组件。CRT 玻璃外壳中含有足够水平的氧化铅(PbO),被认为是危险的,因此需要在废物处理过程中有效地永久封装这种材料。我们研究了在含有废 CRT 玻璃的自密实混凝土(SCC)混合物中添加石灰石粉(LS)对新拌和硬化性能的影响。SCC 混合物采用普通波特兰水泥配制,水泥含量固定在 600kg/m(3),水灰比(w/c)为 0.38。将 CRT 玻璃废料碎玻璃与河砂按 20%或 40%的重量比混合。为了抑制潜在的粘度效应,添加了 5%、10%或 15%重量的石灰石粉。测试了新拌混凝土的坍落度流动时间、坍落度流动直径、V 漏斗流动时间、马歇尔锥形流动时间和凝结时间,以及硬化混凝土的抗压强度和超声波脉冲速度。添加石灰石粉改善了新拌和硬化性能。固化混凝土中的 Pb 浸出水平在 US EPA 允许范围内。

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