易于获得烯酰胺：温和镍催化的烯丙酰胺的烯烃异构化反应。
Easy access to enamides: a mild nickel-catalysed alkene isomerization of allylamides.
机构信息
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, PR China.
出版信息
Chem Commun (Camb). 2013 Sep 18;49(72):7923-5. doi: 10.1039/c3cc43875a. Epub 2013 Jul 30.
PMID:23900613
Abstract
The first Ni-catalysed alkene isomerization of allylamides for the synthesis of enamides was demonstrated. Various substituted N-allylamides were found to be suitable substrates for this isomerization. Isotopic labelling experiments showed that it is an intramolecular hydrogen transfer process.
摘要
首次实现了镍催化的烯丙酰胺的烯烃异构化反应，用于合成烯胺。研究发现，各种取代的 N-烯丙酰胺是该异构化反应的合适底物。同位素标记实验表明，这是一个分子内氢转移过程。
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