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Cu2O形态对TiO2/Cu2O复合材料光催化产氢及化学稳定性的影响

Effect of Cu2O morphology on photocatalytic hydrogen generation and chemical stability of TiO2/Cu2O composite.

作者信息

Zhu Lihong, Zhang Junying, Chen Ziyu, Liu Kejia, Gao Hong

机构信息

Department of Physics, Beihang University, Beijing 100191, PR China.

出版信息

J Nanosci Nanotechnol. 2013 Jul;13(7):5104-8. doi: 10.1166/jnn.2013.7591.

Abstract

Improving photocatalytic activity and stability of TiO2/Cu2O composite is a challenge in generating hydrogen from water. In this paper, the TiO2 film/Cu2O microgrid composite was prepared via a microsphere lithography technique, which possesses a remarkable performance of producing H2 under UV-vis light irradiation, in comparison with pure TiO2 film, Cu2O film and TiO2 film/Cu2O film. More interesting is that in TiO2 film/Cu2O microgrid, photo-corrosion of Cu2O can be retarded. After deposition of Pt on its surface, the photocatalytic activity of TiO2/Cu2O microgrid in producing H2 is improved greatly.

摘要

提高TiO₂/Cu₂O复合材料的光催化活性和稳定性是水制氢领域的一项挑战。本文通过微球光刻技术制备了TiO₂薄膜/Cu₂O微网格复合材料,与纯TiO₂薄膜、Cu₂O薄膜和TiO₂薄膜/Cu₂O薄膜相比,该复合材料在紫外-可见光照射下具有显著的产氢性能。更有趣的是,在TiO₂薄膜/Cu₂O微网格中,Cu₂O的光腐蚀可以得到抑制。在其表面沉积Pt后,TiO₂/Cu₂O微网格产氢的光催化活性得到极大提高。

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