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电模板去湿紫外光固化预聚物薄膜,用于制作具有良好曲率定义的凹微透镜阵列。

Electrically templated dewetting of a UV-curable prepolymer film for the fabrication of a concave microlens array with well-defined curvature.

机构信息

Micro- and Nano-manufacturing Research Center, State Key Laboratory for Manufacturing Systems Engineering, Xi'an Jiaotong University , 28 Xianning Road, Xi'an 710049, People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2013 Oct 23;5(20):9975-82. doi: 10.1021/am402043u. Epub 2013 Aug 14.

Abstract

This paper presents an economic method, based on electrically templated dewetting of a UV-curable prepolymer, for fabricating a concave microlens array (MLA) of high quality and high density. In our strategy, a voltage is applied to an electrode pair consisting of a conductive substrate coated with a UV-curable prepolymer film and a microhole-arrayed silicon template, sandwiching an air gap, to dewet the prepolymer film into a curved air-liquid interface. At or beyond a critical voltage, the curved prepolymer can be pulled quickly into contact with the protrusive underside of the silicon template. Contact of the prepolymer with the template can be detected by monitoring the leaky current in the polymer, followed by a UV curing of the prepolymer. Finally, by separating the mold from the solidified polymer, a concave MLA is obtained. The curvature of the MLA can be well-defined simply by changing the air gap between the mold and prepolymer film. Besides, the dewetting strategy results in a much smaller adhesion area between the mold and solidified polymer structures, which allows for easy separation of the mold from the MLA in a large-area operation.

摘要

本文提出了一种基于电模板去湿的经济方法,用于制造高质量、高密度的凹面微透镜阵列 (MLA)。在我们的策略中,在由涂有 UV 可固化预聚物膜的导电基底和具有微孔阵列的硅模板组成的电极对之间施加电压,夹着气隙,使预聚物膜在空气中脱湿形成弯曲的气液界面。在达到或超过临界电压后,弯曲的预聚物可以迅速与硅模板的突出底面接触。通过监测聚合物中的漏电,可以检测到预聚物与模板的接触,然后对预聚物进行 UV 固化。最后,通过将模具从固化的聚合物中分离出来,得到凹面 MLA。通过改变模具和预聚物薄膜之间的气隙,可以很好地定义 MLA 的曲率。此外,去湿策略导致模具和固化聚合物结构之间的附着面积小得多,这使得模具可以很容易地从大面积操作中的 MLA 中分离出来。

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