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光响应 MOFs：光致变色二芳基乙烯多孔单晶的光诱导开关

Photo-responsive MOFs: light-induced switching of porous single crystals containing a photochromic diarylethene.

机构信息

Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260, USA.

出版信息

Chem Commun (Camb). 2013 Sep 21;49(73):8012-4. doi: 10.1039/c3cc44119a. Epub 2013 Aug 1.

DOI:10.1039/c3cc44119a
PMID:23903589
Abstract

Herein we report the synthesis and characterization of light responsive metal organic framework (MOF) single crystals containing the photochromic diarylethene 1,2-bis(2,5-dimethyl-thien-3-yl)perfluorocyclopentene. Polarized light microscopy on single crystals indicates that the photochrome is preferentially aligned along the c-axis of the host.

摘要

在此，我们报告了光响应金属有机骨架（MOF）单晶的合成与表征，其中包含光致变色二芳基乙烯 1,2-双（2,5-二甲基-3-噻吩基）全氟环戊烯。单晶的偏振光显微镜表明，光致变色体优先沿着主体的 c 轴排列。

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