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基于双(2,4,7,8,9-五甲基二吡咯并[3,4-f:3′,4′-h]苯并[1,2-b:4,5-b′]二噻吩-3-基)甲烷的高灵敏和选择性的“开-关”荧光 Zn2+传感器。

The high sensitive and selective "off-on" fluorescent Zn2+ sensor based on the Bis(2,4,7,8,9-pentamethyldipyrrolylmethene-3-yl)methane.

机构信息

G.A. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, str. Academic, 1, 153045, Ivanovo, Russian Federation,

出版信息

J Fluoresc. 2014 Jan;24(1):13-7. doi: 10.1007/s10895-013-1278-7. Epub 2013 Aug 1.

Abstract

A fluorescent chemosensor based on the 3,3'-bis(dipyrrin) bearing two chromophoric dipyrrin units was synthesized, which showed a strongly enhanced fluorescent intensity in the presence of Zn(2+) ions and a high selectivity toward Zn(2+) ions over a wide range of tested metal ions in organic solvents.

摘要

基于 3,3'-双(二吡咯)的荧光化学传感器合成,该传感器在存在 Zn(2+)离子时表现出强烈增强的荧光强度,并在有机溶剂中对 Zn(2+)离子具有高选择性,对多种测试金属离子具有广泛的选择性。

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