• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

开链四吡咯在功能分子材料科学中与金属离子相遇。

Open-Chain Tetrapyrroles Meet Metal Ions in the Functional Molecular Material Science.

作者信息

Ghosh Aninda, Bhandari Sandipa, Furuta Hiroyuki, Ishida Masatoshi

机构信息

Department of Chemistry, Graduate School of Sciences, Tokyo Metropolitan University, Hachioji, 192-0397, Japan.

Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, Fukuoka, 819-0395, Japan.

出版信息

Chempluschem. 2025 Jun;90(6):e202500090. doi: 10.1002/cplu.202500090. Epub 2025 Apr 6.

DOI:10.1002/cplu.202500090
PMID:40126191
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC12143462/
Abstract

Open-chain tetrapyrroles and their analogues, consisting of four pyrrole rings linked by methylene or methine carbons, originate from natural and synthetic pathways. These compounds exhibit unique structural flexibility due to their extended π-conjugation and tunable coordination with metal ions, enabling precise control over electronic and geometric properties. Such structural versatility makes them promising candidates for chiroptical, optoelectronic, and biorelated applications. By modulating metal coordination and molecular design, their functionalities can be tailored for circularly polarized luminescence, ion sensing, photothermal conversion, and chiral devices. This review highlights recent advancements in open-chain tetrapyrrole-based materials, emphasizing their structure-property relationships and potential for next-generation functional materials.

摘要

开链四吡咯及其类似物由通过亚甲基或次甲基碳连接的四个吡咯环组成，来源于天然和合成途径。这些化合物由于其扩展的π共轭和与金属离子的可调谐配位而表现出独特的结构灵活性，能够精确控制电子和几何性质。这种结构多样性使它们成为手性光学、光电子和生物相关应用的有前途的候选者。通过调节金属配位和分子设计，可以为圆偏振发光、离子传感、光热转换和手性器件量身定制其功能。本综述重点介绍了基于开链四吡咯的材料的最新进展，强调了它们的结构-性能关系以及作为下一代功能材料的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/27c385d65f98/CPLU-90-e202500090-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/7869a2c1572c/CPLU-90-e202500090-g029.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/a2283a94a720/CPLU-90-e202500090-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/dbfb25530217/CPLU-90-e202500090-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/881a2c413027/CPLU-90-e202500090-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/28c56b64d695/CPLU-90-e202500090-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/5e84a78c302c/CPLU-90-e202500090-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/a5e3397a2e8f/CPLU-90-e202500090-g025.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/2b73e27bcdc3/CPLU-90-e202500090-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/3a68f66bbbe5/CPLU-90-e202500090-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/6c1c6b0f8985/CPLU-90-e202500090-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/f813b249713f/CPLU-90-e202500090-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/eca4a306ba07/CPLU-90-e202500090-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/6e2871cb67e4/CPLU-90-e202500090-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/f1de158a413a/CPLU-90-e202500090-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/384e8905ad1b/CPLU-90-e202500090-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/b84139a092d5/CPLU-90-e202500090-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/e0042c2f935a/CPLU-90-e202500090-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/c307b47cbb95/CPLU-90-e202500090-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/7447556b947b/CPLU-90-e202500090-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/7281b4436075/CPLU-90-e202500090-g028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/27c385d65f98/CPLU-90-e202500090-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/7869a2c1572c/CPLU-90-e202500090-g029.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/a2283a94a720/CPLU-90-e202500090-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/dbfb25530217/CPLU-90-e202500090-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/881a2c413027/CPLU-90-e202500090-g017.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/28c56b64d695/CPLU-90-e202500090-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/5e84a78c302c/CPLU-90-e202500090-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/a5e3397a2e8f/CPLU-90-e202500090-g025.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/2b73e27bcdc3/CPLU-90-e202500090-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/3a68f66bbbe5/CPLU-90-e202500090-g016.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/6c1c6b0f8985/CPLU-90-e202500090-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/f813b249713f/CPLU-90-e202500090-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/eca4a306ba07/CPLU-90-e202500090-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/6e2871cb67e4/CPLU-90-e202500090-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/f1de158a413a/CPLU-90-e202500090-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/384e8905ad1b/CPLU-90-e202500090-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/b84139a092d5/CPLU-90-e202500090-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/e0042c2f935a/CPLU-90-e202500090-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/c307b47cbb95/CPLU-90-e202500090-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/7447556b947b/CPLU-90-e202500090-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/7281b4436075/CPLU-90-e202500090-g028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4e4d/12143462/27c385d65f98/CPLU-90-e202500090-g024.jpg

相似文献

1
Open-Chain Tetrapyrroles Meet Metal Ions in the Functional Molecular Material Science.开链四吡咯在功能分子材料科学中与金属离子相遇。
Chempluschem. 2025 Jun;90(6):e202500090. doi: 10.1002/cplu.202500090. Epub 2025 Apr 6.
2
Endowing Metal-Organic Coordination Materials with Chiroptical Activity by a Chiral Anion Strategy.通过手性阴离子策略赋予金属有机配位材料手性光学活性
Chemistry. 2024 May 17;30(28):e202400685. doi: 10.1002/chem.202400685. Epub 2024 Apr 5.
3
Biopyrrin Pigments: From Heme Metabolites to Redox-Active Ligands and Luminescent Radicals.双吡咯色素：从血红素代谢产物到氧化还原活性配体和发光自由基
Acc Chem Res. 2021 Dec 21;54(24):4584-4594. doi: 10.1021/acs.accounts.1c00613. Epub 2021 Dec 6.
4
Indirect Construction of Chiral Metal-Organic Frameworks for Enantioselective Luminescence Sensing.用于对映选择性发光传感的手性金属有机框架的间接构建
Acc Chem Res. 2025 Feb 18;58(4):625-634. doi: 10.1021/acs.accounts.4c00795. Epub 2025 Feb 2.
5
Chiral Organometallic Complexes Derived from Helicenic -Heterocyclic Carbenes (NHCs): Design, Structural Diversity, and Chiroptical and Photophysical Properties.源自螺旋烯基杂环卡宾（NHCs）的手性有机金属配合物：设计、结构多样性以及手性光学和光物理性质
Acc Chem Res. 2024 Oct 15;57(20):2941-2952. doi: 10.1021/acs.accounts.4c00275. Epub 2024 Oct 3.
6
NIR-Circularly Polarized Luminescence from Chiral Complexes of Lanthanides and d-Metals.镧系和 d 金属手性配合物的近红外圆偏振发光。
Angew Chem Int Ed Engl. 2023 Jun 19;62(25):e202302358. doi: 10.1002/anie.202302358. Epub 2023 Apr 20.
7
Postsynthetic Modification of Metal-Organic Layers.金属有机层的合成后修饰
Acc Chem Res. 2025 Mar 18;58(6):812-823. doi: 10.1021/acs.accounts.4c00726. Epub 2025 Mar 6.
8
Chiral Diketopyrrolopyrrole-Based Conjugated Polymers with Intramolecular Rotation-Isomeric Conformation Asymmetry for Near-Infrared Circularly Polarized Light-Sensing Organic Phototransistors.基于手性二酮吡咯并吡咯的共轭聚合物，具有分子内旋转异构构象不对称性，用于近红外圆偏振光传感有机光电晶体管。
ACS Appl Mater Interfaces. 2023 Nov 30. doi: 10.1021/acsami.3c13976.
9
"Point-Line-Plane-Helix" Binuclear Platinum(II) Complexes: Metal-Induced Chirality, Chirality Self-Sorting, and Chiroptical Properties.“点-线-面-螺旋”双核铂（II）配合物：金属诱导手性、手性自分类及手性光学性质
Inorg Chem. 2023 Sep 4;62(35):14152-14157. doi: 10.1021/acs.inorgchem.3c02101. Epub 2023 Aug 8.
10
Circular dichroism and circularly polarized luminescence of ligand-protected molecular metal clusters: insights into structure-chiroptical property relationships.配体保护的分子金属簇的圆二色性和圆偏振发光：对结构-手性光学性质关系的见解。
Nanoscale. 2024 Jun 27;16(25):11914-11927. doi: 10.1039/d4nr01232a.

本文引用的文献

1
Metal-Bridging Cyclic Bilatriene Analogue Affords Stable π-Radicaloid Dyes with Near-Infrared II Absorption.金属桥连环状双三烯类似物提供具有近红外二区吸收的稳定类π-自由基染料。
Angew Chem Int Ed Engl. 2025 Feb 3;64(6):e202418751. doi: 10.1002/anie.202418751. Epub 2024 Dec 17.
2
Probing the Roles of Temperature and Cooperative Effects in Chirality-Induced Spin Selectivity: Photoelectron Spin Polarization in Helical Tetrapyrroles.探究温度和协同效应在手性诱导自旋选择性中的作用：螺旋四吡咯中的光电子自旋极化
J Phys Chem Lett. 2024 Sep 26;15(38):9620-9629. doi: 10.1021/acs.jpclett.4c02209. Epub 2024 Sep 15.
3
Gold Tripyrrindione: Redox Chemistry and Reactivity with Dichloromethane.
金三吡啶二酮：氧化还原化学及其与二氯甲烷的反应活性
Inorg Chem. 2024 Sep 16;63(37):17188-17197. doi: 10.1021/acs.inorgchem.4c02903. Epub 2024 Aug 31.
4
Direct Oxidations of -Tetrakis(pentafluorophenyl)porphyrin: Porphotrilactones and Entry into a Nonbiological Porphyrin Degradation Pathway.-四（五氟苯基）卟啉的直接氧化反应：卟吩三内酯及进入非生物卟啉降解途径
J Org Chem. 2024 May 3;89(9):6584-6589. doi: 10.1021/acs.joc.4c00283. Epub 2024 Apr 23.
5
Metalla-Carbaporphyrinoids Consisting of an Acyclic N-Confused Tetrapyrrole Analogue Served as Stable Near-Infrared-II Dyes.由无环 N-杂四吡咯类似物组成的金属碳卟啉类化合物用作稳定的近红外二区染料。
Angew Chem Int Ed Engl. 2024 Jun 3;63(23):e202405059. doi: 10.1002/anie.202405059. Epub 2024 Apr 29.
6
Making and Breaking Helical Open-Chain Oligopyrroles.构建与拆解螺旋状开链低聚吡咯。
Chempluschem. 2024 May;89(5):e202300708. doi: 10.1002/cplu.202300708. Epub 2024 Jan 30.
7
Metallaantiaromaticity of 10-Platinacorrole Complexes.10-铂卟吩配合物的金属反芳香性
J Am Chem Soc. 2024 Jan 17;146(2):1396-1402. doi: 10.1021/jacs.3c10250. Epub 2024 Jan 3.
8
Strong and Tunable Near-Infrared Circular Dichroism in Helical Tetrapyrrole Complexes.螺旋四吡咯配合物中强烈且可调谐的近红外圆二色性
Chemistry. 2023 Aug 1;29(43):e202300940. doi: 10.1002/chem.202300940. Epub 2023 Jun 28.
9
Milestones in corrole chemistry: historical ligand syntheses and post-functionalization.卟啉化学的里程碑：历史配体合成和后功能化。
Chem Soc Rev. 2023 Jan 25;52(2):573-600. doi: 10.1039/d1cs01137e.
10
Bile pigments in emergency and critical care medicine.急诊与重症医学中的胆色素
Eur J Med Res. 2022 Oct 29;27(1):224. doi: 10.1186/s40001-022-00863-0.