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[缅甸深绿色翡翠的光谱]

[Spectra of dark green jade from Myanmar].

作者信息

Mao Jian, Chai Lin-Tao, Guo Shou-Guo, Fan Jian-Liang, Bao Feng

机构信息

Gemstone Testing Center of East China University of Science and Technology, Shanghai 200237, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2013 May;33(5):1388-91.

Abstract

Chemical compositions and spectral characteristics of one type of dark green jades assumed from omphacite jadeite from Myanmar jadeite mining area were studied by X-ray powder diffraction(XRD), X-ray fluorescence spectra(XRF), Raman spectra(RM) and UV-Vis Spectroscopy, etc. Based on testing by XRD and XRF, it was shown that it belongs to iron-enriched plagioclase, including albite and anorthite. The compositions range is between Ab0.731 An0.264 Or0.004 and Ab0.693 An0.303 Or0.004. Raman spectra of samples, albite jade and anorthite were collected and analyzed. Additionally, the distributions of Si, Al in the crystal structure were also discussed. UV-Vis spectra showed that dark green hue of this mineral is associated with d--d electronic transition of Fe3+ and Cr3+.

摘要

采用X射线粉末衍射(XRD)、X射线荧光光谱(XRF)、拉曼光谱(RM)以及紫外-可见光谱等方法对采自缅甸翡翠矿区的一种由绿辉石翡翠假象而成的墨绿色玉石的化学成分和光谱特征进行了研究。通过XRD和XRF测试表明,其属于富铁斜长石,包括钠长石和钙长石。成分范围在Ab0.731An0.264Or0.004和Ab0.693An0.303Or0.004之间。收集并分析了样品、钠长石玉和钙长石的拉曼光谱。此外,还讨论了晶体结构中Si、Al的分布情况。紫外-可见光谱表明,该矿物的墨绿色调与Fe3+和Cr3+的d-d电子跃迁有关。

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