Textile Research Division, National Research Center, Cairo, Egypt.
Carbohydr Polym. 2013 Sep 12;97(2):783-93. doi: 10.1016/j.carbpol.2013.05.063. Epub 2013 Jun 3.
Innovative/efficient finishing systems for imparting multi-functional properties to cotton/polyester and viscose/polyester blends were developed. Factors affecting the extent of functionalization including type and concentration of the nano-hybrid, i.e. silver nanoparticles/polyvinyl pyrolidone hybrid (Ag-NP's/PVP) or zinc oxide nanoparticles/hyperbranched polyamide-amine hybrid (ZnO-NP's/HBPAA), concentration of Basic Blue 9, or chitosan and sequence of treatment using citric acid as cross-linker were reported. Loading of β-CD, with its hydrophobic cavities, onto the cross-linked substrates and subsequent treatment with Neem-oil, Lavender-oil or 4-hydroxybenzophenone was also studied. The obtained products exhibit a remarkable easy care, antibacterial and/or UV-blocking functional properties. The improvement in the imparted properties and durability to wash is governed by type and amount of loaded active ingredients. Mode of interactions was suggested, and surface modifications together with composition of selected samples were also confirmed by SEM images and EDX spectra.
开发了用于赋予棉/聚酯和粘胶/聚酯混合物多种功能特性的创新/高效整理系统。影响功能化程度的因素包括纳米杂化剂的类型和浓度,例如银纳米颗粒/聚乙烯吡咯烷酮杂化(Ag-NP's/PVP)或氧化锌纳米颗粒/超支化聚酰胺-胺杂化(ZnO-NP's/HBPAA)、碱性蓝 9 或壳聚糖的浓度,以及使用柠檬酸作为交联剂的处理顺序。还研究了将β-CD(其具有疏水性空腔)负载到交联的基质上,然后用印楝油、薰衣草油或 4-羟基二苯甲酮进行处理。所得产物表现出显著的易护理、抗菌和/或防紫外线功能特性。所赋予的性能的改善以及耐洗性取决于负载的活性成分的类型和数量。提出了相互作用的模式,并且还通过 SEM 图像和 EDX 光谱证实了表面改性以及选定样品的组成。