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[四川省女性血清中多溴二苯醚的组成及分布特征]

[Compositions and distribution characteristics of polybrominated diphenyl ethers in serum of women from Sichuan province].

作者信息

Shao Min, Chen Yong-heng, Li Xiao-yu

机构信息

Environmental Science and Engineering Institute of Guangzhou University, Guangzhou 510006, China.

出版信息

Huan Jing Ke Xue. 2013 May;34(5):1877-81.

Abstract

The serum concentrations of polybrominated diphenyl ethers (PBDEs) in women from Sichuan province were detected via gas chromatograph-mass spectrometry in selected ion monitoring mode (SIM). Based on the experimental data, the compositions and distribution characteristics of PBDEs as well as pollution resource were also explored. Among these 11 congeners of PBDEs detected, BDE-209 was the dominant congener accounting for 63.57% -90.34% in the total PBDEs, followed by BDE-66,-99 and-100. The concentrations of BDE-209 ranged from 0.12 to 2.38 microg x L(-1) and the mean concentration was 0.63 microg x L(-1). Other congeners of these 11 PBDEs could not be detected. The data indicated that the major pollution came from deca-BDE, followed by tetra-BDE and penta-BDE. At the mean time, this result also showed that the pollution of PBDEs in Sichuan province was still at a lower level for ordinary women when compared to the data from other countries.

摘要

采用气相色谱 - 质谱联用仪的选择离子监测模式(SIM)检测了四川省女性血清中多溴二苯醚(PBDEs)的浓度。基于实验数据,还探讨了PBDEs的组成、分布特征以及污染来源。在所检测出的11种PBDEs同系物中,BDE - 209是主要同系物,占总PBDEs的63.57% - 90.34%,其次是BDE - 66、- 99和 - 100。BDE - 209的浓度范围为0.12至2.38μg x L(-1),平均浓度为0.63μg x L(-1)。这11种PBDEs中的其他同系物未被检测到。数据表明主要污染来自十溴二苯醚,其次是四溴二苯醚和五溴二苯醚。同时,该结果还表明,与其他国家的数据相比,四川省普通女性中PBDEs的污染仍处于较低水平。

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