Department of Chemistry and Biochemistry, University of Denver , Denver, Colorado 80208, USA.
Environ Sci Technol. 2013 Aug 20;47(16):9523-9. doi: 10.1021/es401487b. Epub 2013 Aug 8.
California and Federal emissions regulations for 2007 and newer heavy-duty diesel engines require an order of magnitude reduction in particulate matter and oxides of nitrogen spurring the introduction of new aftertreatment systems. Since 2008, four emission measurement campaigns have been conducted at a Port of Los Angeles location and an inland weigh station in the South Coast Air Basin of California. Fuel specific oxides of nitrogen emissions at the Port have decreased 12% since 2010 while infrared opacity (a measure of particulate matter) remained low, showing no diesel particulate filter deterioration. The weigh station truck's fuel specific oxides of nitrogen emission reductions since 2010 (18.5%) almost double the previous three year's reductions and are the result of new trucks using selective catalytic reduction systems. Trucks at the weigh station equipped with these systems have a skewed oxides of nitrogen emissions distribution (half of the emissions were from 6% of the measurements) and had significantly lower emissions than similarly equipped Port trucks. Infrared thermographs of truck exhaust pipes revealed that the mean temperature observed at the weigh station (225 ± 4.5 °C) was 70 °C higher than for Port trucks, suggesting that the catalytic aftertreatment systems on trucks at our Port site were often below minimum operating temperatures.
加利福尼亚州和联邦 2007 年及以后的重型柴油发动机排放法规要求大幅度减少颗粒物和氮氧化物,从而推动了新的后处理系统的引入。自 2008 年以来,在洛杉矶港和加利福尼亚南海岸大气盆地的内陆称重站进行了四次排放测量活动。自 2010 年以来,港口的燃料特定氮氧化物排放量减少了 12%,而红外不透明度(颗粒物的一种衡量标准)保持在较低水平,表明柴油颗粒过滤器没有恶化。自 2010 年以来,称重站卡车的燃料特定氮氧化物排放量减少了 18.5%,几乎是前三年减排量的两倍,这是因为新卡车使用了选择性催化还原系统。在称重站配备这些系统的卡车的氮氧化物排放量分布呈偏态(排放量的一半来自 6%的测量值),并且排放量明显低于配备类似系统的港口卡车。卡车排气管的红外热图显示,称重站观测到的平均温度(225 ± 4.5°C)比港口卡车高 70°C,这表明我们港口的卡车的催化后处理系统经常低于最低运行温度。