使用确定的铁-膦催化剂氢化硝基芳烃。
Hydrogenation of nitroarenes using defined iron-phosphine catalysts.
机构信息
Leibniz-Institut für Katalyse e.V., Albert Einstein Straße. 29a, 18059 Rostock, Germany.
出版信息
Chem Commun (Camb). 2013 Oct 14;49(80):9089-91. doi: 10.1039/c3cc42983k. Epub 2013 Aug 9.
PMID:23928899
Abstract
A novel iron-catalyzed hydrogenation of nitroarenes to the corresponding amines is reported. An in situ combination of Fe(BF4)2·6H2O and phosphine allows for highly selective hydrogenation of a broad range of aromatic and nitroarenes tolerating different functional groups.
摘要
本文报道了一种新型铁催化的硝基芳烃加氢反应，生成相应的胺。通过原位组合 Fe(BF4)2·6H2O 和膦，可实现广泛的芳香族和硝基芳烃的高选择性加氢，同时容忍不同的官能团。
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