Nasri H, Scheidt W R
Department of Chemistry and Biochemistry, University of Notre Dame, Indiana 46556.
Acta Crystallogr C. 1990 Jun 15;46 ( Pt 6):1096-8. doi: 10.1107/s0108270190000208.
[Os(C36H44N4)O2].C6H5Cl, Mr = 867.53, triclinic, P1, a = 8.177 (1), b = 10.668 (1), c = 11.791 (1) A, a = 73.91 (1), beta = 83.18 (1), gamma = 75.07 (1) degree, V = 953.6 A3, Z = 1, Dx = 1.51 g cm-3, Dm = 1.50 g cm-3, Mo K alpha, lambda = 0.71073 A, mu = 34.5 cm-1, F(000) = 438, T = 293 K, R = 0.048 for 5721 unique observed reflections. The Os atom is centered in the porphinato plane with an average Os-N = 2.052 (6) A and Os-O = 1.745 (5) A. The 24-atom porphyrin core is effectively planar with the largest deviation from the mean plane less than 0.02 A.
[Os(C₃₆H₄₄N₄)O₂].C₆H₅Cl，Mr = 867.53，三斜晶系，P1，a = 8.177(1)，b = 10.668(1)，c = 11.791(1) Å，α = 73.91(1)，β = 83.18(1)，γ = 75.07(1)°，V = 953.6 ų，Z = 1，Dx = 1.51 g cm⁻³，Dm = 1.50 g cm⁻³，Mo Kα，λ = 0.71073 Å，μ = 34.5 cm⁻¹，F(000) = 438，T = 293 K，对于5721个独立观测反射，R = 0.048。Os原子位于卟啉平面中心，平均Os-N = 2.052(6) Å，Os-O = 1.745(5) Å。24原子的卟啉核心实际上是平面的，与平均平面的最大偏差小于0.02 Å。
