[Pd(IPr*(OMe))(cin)Cl]（cin = 肉桂基）催化的碳-硫键形成。
Carbon-sulfur bond formation catalyzed by [Pd(IPr*(OMe))(cin)Cl] (cin = cinnamyl).
机构信息
EaStCHEM School of Chemistry, University of St. Andrews , St. Andrews, Fife KY16 9ST, U.K.
出版信息
J Org Chem. 2013 Sep 20;78(18):9303-8. doi: 10.1021/jo401492n. Epub 2013 Sep 10.
PMID:23937148
Abstract
The newly prepared complex [Pd(IPr*(OMe))(cin)(Cl)] provides high catalytic activity for carbon-sulfur cross-coupling reactions. Nonactivated and deactivated aryl halides were successfully coupled with a large variety of aryl- and alkylthiols using this well-defined palladium N-heterocyclic carbene (NHC) complex.
摘要
新制备的配合物 [Pd(IPr*(OMe))(cin)(Cl)] 对碳-硫交叉偶联反应具有很高的催化活性。使用这种定义明确的钯 N-杂环卡宾 (NHC) 配合物，可成功地将非活化和去活化的芳基卤化物与各种芳基和烷基硫醇进行偶联。
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