基于二氟二氧代膦酸的中空六核镧系元素（III）簇，其表面修饰有四硫富瓦烯配体。
Difluorodioxophosphate-based hollow hexanuclear lanthanide(III) clusters decorated with tetrathiafulvalene ligands.
机构信息
Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS, Université de Rennes 1 , 263 Avenue du Général Leclerc, 35042 Rennes Cedex, France.
出版信息
Inorg Chem. 2013 Sep 3;52(17):9711-3. doi: 10.1021/ic4012839. Epub 2013 Aug 14.
The galvanostatic reaction of the [4,5-bis(2-pyridyl-N-oxidemethylthio)]-4',5'-methyldithiotetrathiafulvalene ligand with lanthanide ions in the presence of hexafluorophosphate (PF6(-)) anions afforded the highest-nuclearity lanthanide clusters decorated by tetrathiafulvalene-based ligands thanks to the original partial hydrolysis of the PF6(-) anions in difluorodioxophosphate (PO2F2(-)) bridging ligands.
在六氟磷酸根（PF6(-)）阴离子存在下，[4,5-双（2-吡啶-N-氧化甲基硫代）]-4',5'-甲基二硫代四噻吩并二噻吩富勒烯配体与镧系离子的恒电流反应，由于 PF6(-)阴离子在二氟二氧膦（PO2F2(-)）桥联配体中的原始部分水解，得到了最高核数的镧系元素簇，这些簇由基于四噻吩并二噻吩的配体修饰。
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