硼烷-联噻吩-BODIPY 三联体：有趣的三色彩色发射和对氟离子的选择性荧光响应。
A borane-bithiophene-BODIPY triad: intriguing tricolor emission and selective fluorescence response towards fluoride ions.
机构信息
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India.
出版信息
Chem Commun (Camb). 2013 Oct 4;49(76):8558-60. doi: 10.1039/c3cc42979b.
PMID:23945837
Abstract
The structure and photophysical properties of a new triad (borane–bithiophene–BODIPY) 1 have been investigated. Triad 1 exhibits unprecedented tricolour emission when excited at the borane centred high energy absorption band and also acts as a selective fluorescent and colorimetric sensor for fluoride ions with ratiometric response. The experimental results are supported by computational studies.
摘要
研究了一种新型三联体（硼烷-联噻吩-BODIPY）1 的结构和光物理性质。三联体 1 在硼烷中心高能吸收带激发时表现出前所未有的三色彩色发射，并且还可以作为对氟离子具有比率响应的选择性荧光和比色传感器。实验结果得到了计算研究的支持。
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