具有自贯穿和互贯穿固有特征的金属离子导向的金属-有机轮烷框架。
Metal ion directed metal-organic rotaxane frameworks with intrinsic features of self-penetration and interpenetration.
机构信息
Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China.
出版信息
Chem Commun (Camb). 2013 Oct 4;49(76):8555-7. doi: 10.1039/c3cc43990a.
Three novel self-catenated 4-connected uninodal (6(5)·8)- metal-organic rotaxane frameworks (MORFs) containing cucurbit[6]uril were constructed from the in situ trans/cis-configuration (1 : 1) of rotaxanes by taking advantage of a d(10) metal ion directed synthesis. It was revealed that the effect of hydrogen bonds and π-π stacking interactions play significant roles in the self-assembly process.
三种新型的自连接 4 连接单节点（6(5)·8）-金属有机轮烷框架（MORFs），其中包含了葫芦脲[6]脲，是通过利用 d(10)金属离子导向合成，从轮烷的原位 trans/cis-构型（1 : 1）构建而成。结果表明，氢键和π-π堆积相互作用对自组装过程起着重要作用。
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